Jurgen Klopp’s champions begin the first defence of their title by welcoming the winners of the Championship to Anfield.
It will be the first league meeting between the sides since 2004 as they prepare for an evening kick-off on September 12.
Sky are also covering Brighton’s clash with Chelsea at the Amex Stadium on Monday Night Football to complete their broadcasting duties for the opening weekend.
All three of Liverpool’s opening fixtures will be shown on Sky with their matches away at Chelsea and home to Arsenal also in the 12-game announcement.
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Two of Man City’s fixtures are also being screened, with their tricky trip to Wolves on the night of Monday September 21 and their showdown with Leicester at The Etihad six days later part of the selection.
West Brom vs Chelsea and Fulham vs Aston Villa make up the list with further announcements to come once the season gets under way.
Sky are sharing the broadcasting again this season with BT Sport and Amazon Prime, both of whom are yet to announce their fixtures.
Here are the first fixtures being shown live by Sky Sports:
Sat 12 Sep: Liverpool vs Leeds Utd – 5.30pm
Sun 13 Sep: West Brom vs Leicester City – 2pm
Sun 13 Sep: Tottenham vs Everton – 4.30pm
Mon 14 Sep:Brighton vs Chelsea – 8pm
Sat 19 Sep: Man Utd vs Crystal Palace – 5.30pm
Sun 20 Sep: Arsenal vs West Ham Utd – 2pm
Sun 20 Sep: Chelsea vs Liverpool – 4.30pm
Mon 21 Sep: Wolves vs Man City – 8pm
Sat 26 Sep: West Brom vs Chelsea – 5.30pm
Sun 27 Sep: Fulham vs Aston Villa – 2pm
Sun 27 Sep: Man City vs Leicester City – 4.30pm
Mon 28 Sep: Liverpool vs Arsenal – 8pm
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